Stephen Colbert w/ The Black Belles – “Charlene (I’m Right Behind You)”

For Jack White and Third Man Records’ final segment on The Colbert Report tonight, the pair announced today’s surprise release of their 7″ single: a new recording of Colbert’s ’80s love song “Charlene (I’m Right Behind You)” backed by TMR’s Black Belles. You can pick up a copy here or here and watch all six clips from this week’s White-Colbert festivities thataway. Meanwhile, this epic comedy-music collaboration will make their live debut via a Rolling Record Store performance at NYC’s High Line Park this morning.